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Sweetness in onions is more accurately termed 'the lack of pungency'. Sugar levels really don't determine if an onion will be sweet. Some pungent onions actually have more sugar in them than "sweet onions".
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The sweet flavor or sugar is masked out by a very high presence of sulfur compounds. The low amount of sulfur compounds and high water content in sweet onions allows the sugar flavor to come through.
 
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